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The proportions of these components may vary between horizons in a soil
or between similar horizons in different soils. The ratio of soil water
to soil air depends upon whether the soil is wet or dry. The mineral
matter, composed of particles ranging in size from the submicroscopic to
gravel or even rocks in some cases, accounts for the bulk of the dry
weight of the soil and occupies some 40 to 60% of the soil volume.
Organic matter, derived from the waste products and remains of plants
and animals, occurs in largest amounts in the surface soil, but even
here seldom accounts for more than 10% of the dry weight of the soil.
Soils are very porous bodies. Some 40 to 60% of the volume is interparticle space, or pore space.
The pores, highly irregular in shape and size but almost all
interconnected by passages, contain soil water, soil air, or both of
these. The soil water reacts chemically with the soil solids and
usually contains dissolved substances and perhaps suspended particles.
The soil air approaches equilibrium with atmospheric air through
movement of individual gases.
Bedrock is the ultimate source of the inorganic component in soils.
When rock is exposed at the surface of the earth's crust, it is broken
down into smaller and smaller fragments by physical forces. The
fragments may be altered or decomposed by chemical reaction of mineral
matter with water and air. Hundreds, thousands, or even millions of
years may be required for the weathering or physical and chemical
alteration of rock to produce the ultimate end products in soils. Once
particles reach a sufficiently small size they can be moved by wind,
water or ice when exposed at the surface. It is common, therefore, for
small particles to be moved from one location to another. A single
particle might occur in several different soils over a period of 100,000
years. Eventually, these particles or their decomposition products
reach the ocean where they are redeposited as marine sediments.
The silicate group of minerals is dominant in soil systems. The terms,
clay mineral and layer silicate, are used almost interchangeably. The
dominant chemical elements in silicate clays are oxygen, silicon,
aluminum and iron. Important constituents in relatively small amounts
are potassium, calcium, magnesium and sodium. Other elements occur in
very small amounts in silicates. Carbonates, oxides, phosphates and
sulfates are other mineral groups that occur commonly in parent
materials.

Soils are porous and open bodies, yet they retain water. They contain
mineral particles of many shapes and sizes and organic material which is
colloidal (particles so small they remain suspended in water) in
character. The solid particles lie in contact one with the other, but
they are seldom packed as closely together as possible.
Texture
The size distribution of primary mineral particles, called soil texture,
has a strong influence on the properties of a soil. Particles larger
than 2 mm in diameter are considered inert. Little attention is paid to
them unless they are boulders that interfere with manipulation of the
surface soil. Particles smaller than 2 mm in diameter are divided into
three broad categories based on size. Particles of 2 to 0.05 mm
diameter are called sand; those of 0.05 to 0.002 mm diameter are silt; and the <0.002 mm particles are clay.
The texture of soils is usually expressed in terms of the percentages
of sand, silt, and clay. To avoid quoting exact percentages, 12
textural classes have been defined. Each class, named to identify the
size separate or separates having the dominant impact on properties,
includes a range in size distribution that is consistent with a rather
narrow range in soil behavior. The loam textural class contains
soils whose properties are controlled equally by clay, silt and sand
separates. Such soils tend to exhibit good balance between large and
small pores; thus, movement of water, air and roots is easy and water
retention is adequate. Soil texture, a stable and an easily determined
soil characteristic, can be estimated by feeling and manipulating a
moist sample, or it can be determined accurately by laboratory analysis.
Soil horizons are sometimes separated on the basis of differences in
texture.
Structure
Anyone who has ever made a mud ball knows that soil particles have a
tendency to stick together. Attempts to make mud balls out of pure sand
can be frustrating experiences because sand particles do not cohere
(stick together) as do the finer clay particles. The nature of the
arrangement of primary particles into naturally formed secondary
particles, called aggregates, is soil structure. A sandy
soil may be structureless because each sand grain behaves independently
of all others. A compacted clay soil may be structureless because the
particles are clumped together in huge massive chunks. In between these extremes, there is the granular structure of surface soils and the blocky structure of subsoils. In some cases subsoils may have platy
or columnar types of structure. Structure may be further described in
terms of the size and stability of aggregates. Structural class is
based on aggregate size, while structural grade is based on aggregate
strength. Soil horizons can be differentiated on the basis of
structural type, class, or grade.
What causes aggregates to form and what holds them together? Clay
particles cohere to each other and adhere to larger particles under the
conditions that prevail in most soils. Wetting and drying, freezing and
thawing, root and animal activity, and mechanical agitation are
involved in the rearranging of particles in soils--including destruction
of some aggregates and the bringing together of particles into new
aggregate groupings. Organic materials, especially microbial cells and
waste products, act to cement aggregates and thus to increase their
strength. On the other hand, aggregates may be destroyed by poor
tillage practices, compaction, and depletion of soil organic matter.
The structure of a soil, therefore, is not stable in the sense that the
texture of a soil is stable. Good structure, particularly in fine
textured soils, increases total porosity because large pores occur
between aggregates, allowing penetration of roots and movement of water
and air.
Consistence
Consistence is a description of a soil's physical condition at
various moisture contents as evidenced by the behavior of the soil to
mechanical stress or manipulation. Descriptive adjectives such as hard,
loose, friable, firm, plastic, and sticky are used for consistence.
Soil consistence is of fundamental importance to the engineer who must
move the material or compact it efficiently. The consistence of a soil
is determined to a large extent by the texture of the soil, but is
related also to other properties such as content of organic matter and
type of clay minerals.
Color
The color of objects, including soils, can be determined by minor
components. Generally, moist soils are darker than dry ones and the
organic component also makes soils darker. Thus, surface soils tend to
be darker than subsoils. Red, yellow and gray hues of subsoils reflect
the oxidation and hydration states or iron oxides, which are reflective
of predominant aeration and drainage characteristics in subsoil. Red
and yellow hues are indicative of good drainage and aeration, critical
for activity of aerobic organisms in soils. Mottled zones, splotches of
one or more colors in a matrix of different color, often are indicative
of a transition between well drained, aerated zones and poorly drained,
poorly aerated ones. Gray hues indicate poor aeration. Soil color
charts have been developed for the quantitative evaluation of colors.

Major Elements
Eight chemical elements comprise the majority of the mineral matter in
soils. Of these eight elements, oxygen, a negatively-charged ion (anion)
in crystal structures, is the most prevalent on both a weight and
volume basis. The next most common elements, all positively-charged
ions (cations), in decreasing order are silicon, aluminum, iron,
magnesium, calcium, sodium, and potassium. Ions of these elements
combine in various ratios to form different minerals. More than eighty
other elements also occur in soils and the earth's crust, but in much
smaller quantities.
Soils are chemically different from the rocks and minerals from which
they are formed in that soils contain less of the water soluble
weathering products, calcium, magnesium, sodium, and potassium, and more
of the relatively insoluble elements such as iron and aluminum. Old,
highly weathered soils normally have high concentrations of aluminum and
iron oxides.
The organic fraction of a soil, although usually representing much less
than 10% of the soil mass by weight, has a great influence on soil
chemical properties. Soil organic matter is composed chiefly of
carbon, hydrogen, oxygen, nitrogen and smaller quantities of sulfur and
other elements. The organic fraction serves as a reservoir for the
plant essential nutrients, nitrogen, phosphorus, and sulfur, increases
soil water holding and cation exchange capacities, and enhances soil
aggregation and structure.
The most chemically active fraction of soils consists of colloidal clays
and organic matter. Colloidal particles are so small (< 0.0002 mm)
that they remain suspended in water and exhibit a very large surface
area per unit weight. These materials also generally exhibit net
negative charge and high adsorptive capacity. Several different
silicate clay minerals exist in soils, but all have a layered structure.
Montmorillonite, vermiculite, and micaceous clays are examples of 2:1 clays, while kaolinite is a 1:1 clay
mineral. Clays having a layer of aluminum oxide (octahedral sheet)
sandwiched between two layers of silicon oxide (tetrahedral sheets) are
called 2:1 clays. Clays having one tetrahedral sheet bonded to one
octahedral sheet are termed 1:1 clays.
Cation Exchange
Silicate clays and organic matter typically possess net negative charge
because of cation substitutions in the crystalline structures of clay
and the loss of hydrogen cations from functional groups of organic
matter. Positively-charged cations are attracted to these
negatively-charged particles, just as opposite poles of magnets attract
one another. Cation exchange is the ability of soil clays and
organic matter to adsorb and exchange cations with those in soil
solution (water in soil pore space). A dynamic equilibrium exists
between adsorbed cations and those in soil solution. Cation adsorption
is reversible if other cations in soil solution are sufficiently
concentrated to displace those attracted to the negative charge on clay
and organic matter surfaces. The quantity of cation exchange is
measured per unit of soil weight and is termed cation exchange capacity.
Organic colloids exhibit much greater cation exchange capacity than
silicate clays. Various clays also exhibit different exchange
capacities. Thus, cation exchange capacity of soils is dependent upon
both organic matter content and content and type of silicate clays.
Cation exchange capacity is an important phenomenon for two reasons:
- exchangeable cations such as calcium, magnesium, and potassium are readily available for plant uptake and
- cations adsorbed to exchange sites are more resistant to leaching, or downward movement in soils with water.
Movement of cations below the rooting depth of plants is associated with
weathering of soils. Greater cation exchange capacities help decrease
these losses. Pesticides or organics with positively charged functional
groups are also attracted to cation exchange sites and may be removed
from the soil solution, making them less subject to loss and potential
pollution.
Calcium (Ca++) is normally the predominant exchangeable
cation in soils, even in acid, weathered soils. In highly weathered
soils, such as oxisols, aluminum (Al+3) may become the dominant exchangeable cation.
The energy of retention of cations on negatively charged exchange sites
varies with the particular cation. The order of retention is: aluminum
> calcium > magnesium > potassium > sodium > hydrogen.
Cations with increasing positive charge and decreasing hydrated size are
most tightly held. Calcium ions, for example, can rather easily
replace sodium ions from exchange sites. This difference in
replaceability is the basis for the application of gypsum (CaSO4) to reclaim sodic soils (those with >
15% of the cation exchange capacity occupied by sodium ions). Sodic
soils exhibit poor structural characteristics and low infiltration of
water.
The cations of calcium, magnesium, potassium, and sodium produce an alkaline reaction in water and are termed bases or basic cations. Aluminum and hydrogen ions produce acidity in water and are called acidic cations. The percentage of the cation exchange capacity occupied by basic cations is called percent base saturation. The greater the percent base saturation, the higher the soil pH.
Soil pH
Soil pH is probably the most commonly measured soil chemical property
and is also one of the more informative. Like the temperature of the
human body, soil pH implies certain characteristics that might be
associated with a soil. Since pH (the negative log of the hydrogen ion
activity in solution) is an inverse, or negative, function, soil pH
decreases as hydrogen ion, or acidity, increases in soil solution. Soil
pH increases as acidity decreases.
A soil pH of 7 is considered neutral. Soil pH values greater than 7
signify alkaline conditions, whereas those with values less than 7
indicate acidic conditions. Soil pH typically ranges from 4 to 8.5, but
can be as low as 2 in materials associated with pyrite oxidation and
acid mine drainage. In comparison, the pH of a typical cola soft drink
is about 3.
Soil pH has a profound influence on plant growth. Soil pH affects the
quantity, activity, and types of microorganisms in soils which in turn
influence decomposition of crop residues, manures, sludges and other
organics. It also affects other nutrient transformations and the
solubility, or plant availability, of many plant essential nutrients.
Phosphorus, for example, is most available in slightly acid to slightly
alkaline soils, while all essential micronutrients, except molybdenum,
become more available with decreasing pH. Aluminum, manganese, and even
iron can become sufficiently soluble at pH < 5.5 to become toxic to
plants. Bacteria which are important mediators of numerous nutrient
transformation mechanisms in soils generally tend to be most active in
slightly acid to alkaline conditions.

Soils, like other naturally occurring things, come in great variety and
exhibit great ranges of properties. Using measurable and observable
properties, such as the kind and arrangement of soil horizons, soils can
be characterized and named. The soil series is the lowest category within soil taxonomy
(classification system). All soils within a single series have uniform
differentiating characteristics and arrangement of horizons. This does
not mean that all soils within a series are identical; it does mean
that they have the same horizonation, but the horizons may be of
different thickness, color, structure, etc. within prescribed limits.
Some 15,000 soil series have been described and named in the United
States. Most series names are taken from the name of a town, city,
county, river or other constructed or natural feature near the location
where the soil is first described and named.
All of the soils within a series will have developed in the same kind of
parent material with comparable drainage characteristics and will be of
similar age. The effects of climate and biological activity will have
been very similar. Consequently, the soils within a series exhibit like
properties and respond in like fashion to usage or manipulation.
Higher levels of classification are the family, subgroup, great group,
suborder and order. All these categories are given generic names which
convey as much information as possible about the soil series to be
classified within the group. Eleven soil orders form the highest level
of classification. Soils classified within each order show only small
differences in the kinds and relative strengths of processes that tend
to develop soil horizons.
Considerable effort by soil scientists has been expended, and continues
to be expended, in surveying soil resources. These surveys, when done
in a detailed manner, require a soil scientist to traverse the landscape
at frequent intervals, stopping periodically to auger or dig into the
soil. The soil surveyor plots the occurrence of soils on a map which is
subsequently formalized and eventually published in a soil survey
report which includes not only the soil maps for a given area, usually a
county, but all types of information about the county as well as
descriptions of the properties of the soils in the area, their present
and potential uses, and potential problems associated with the
utilization of the soils for both agricultural and engineering purposes.
Such reports are very expensive in terms of labor and money, but they
contain information that is of great value to those who utilize soils
for any purpose. Unfortunately, many who could use the information in
soil survey reports to great advantage do not know that the reports are
available. With increased emphasis on planning, which includes land
use, on county, state and regional bases, more utilization of soil
survey information is being made and even more detailed and more modern
soil surveys are being urgently requested in many areas. Much of this
information is being digitized for electronic transmission.
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